Publications
Bioinspired Oxidation Catalysis with Iron Complexes
G. Zámbó, C. Esslinger, M. Sauer, I. Rüter, R. Reich, S. Demeshko, F. Meyer, and F. Kühn
Exploring the impact of abnormal coordination in macrocyclic N-heterocyclic carbene ligands on bio-inspired iron epoxidation catalysis
Catal. Sci. Technol., 2024, 14, 6259 - 6269.
T. Josephy, R. Kumar, K. Bleher, F. Röhs, T. Glaser, G. Rajaraman, and P. Comba
Synthesis, Characterization, and Reactivity of Bispidine-Iron(IV)-Tosylimido Species
Inorg. Chem., 2024, 63, 12109-1211.
L. Siebe, C. Butenuth, A. Stammler, H. Bögge, S. Walleck, and T. Glaser
"Generation and Reactivity of µ-1,2-Peroxo CuIICuII and Bis-µ-oxo CuIIICuIII Species and Catalytic Hydroxylation of Benzene to Phenol with Hydrogen Peroxide"
Inorg. Chem., 2024, 63, 2627-2639.
L. Siebe, C. Butenuth, A. Köhler, A. Stammler, J. Oldengott, H. Bögge, and T. Glaser
"Synthesis of Asymmetric Variants in a Dinucleating Ligand Family and Application for Dinuclear Copper(II) Complexes"
Eur. J. Inorg. Chem., 2024, DOI 10.1002/ejic.202400142.
F. Depenbrock, T. Limpke, A. Stammler, J. Oldengott, H. Bögge, and T. Glaser
"Increasing the electron donation in a dinucleating ligand family: molecular and electronic structures in a series of CoIICoII complexes"
Dalton Trans., 2024, 53, 9554-9567.
R. Kumar, A. Ansari, P. Comba, and G. Rajaraman
"Rebound or Cage Escape? The Role of the Rebound Barrier for the Reactivity of Non-heme High-valent FeIV=O species"
Chem. Eur. J., 2023, e202303300.
G. Mukherjee, G. Velmurugan, M. Kerscher, J. Kumar Satpathy, C. V. Sastri, and P. Comba
"Mechanistic Insights into Amphoteric Reactivity of an Iron-Bispidine Complex"
Chem. Eur. J., 2023, e202303127.
F. Depenbrock, T. Limpke, E. Bill, D. J. SantaLucia, M. van Gastel, S. Walleck, J. Oldengott, A. Stammler, H. Bögge, and T. Glaser
"Reactivities and Electronic Structures of µ-1,2-Peroxo and µ-1,2-Superoxo CoIIICoIII Complexes: Electrophilic Reactivity and O2 Release Induced by Oxidation"
Inorg. Chem., 2023, 62, 17913-17930.
S. Finke, A. Stammler, J. Oldengott, S. Walleck, and T. Glaser
"Direct and remote control of electronic structures and redox potentials in µ-diferric complexes"
Dalton Trans., 2023, 52, 17548-17561.
J. Hädeler, G. Velmurugan, R. Lauer, R. Radhamani, F. Keppler, and P. Comba
"Natural Abiotic Iron-Oxido-Mediated Formation of C1 and C2 Compounds from Environmentally Importand Methyl-Substituted Substrates"
J. Am. Chem. Soc., 2023, 145, 24590-24602.
Y. Li, R. Singh, A. Sinha, G. C. Lisensky, M. Haukka, J. Nilsson, S. Yiga, S. Demeshko, S. J. Gross, S. Dechert, A. Gonzalez, G. Farias, O. F. Wendt, F. Meyer, and E. Nordlander
"Nonheme Fe(IV)=O Complexes Supported by Four Pentadentate Ligands: Reactivity toward H- and O- Atom Transfer Processes"
Inorg. Chem. , 2023, 62, 18338-18356.
T. P. Schlachta, G. G. Zámbó, M. J. Sauer, I. Rüter, C. A. Hoefer, S. Demeshko, F. Meyer, and F. E. Kühn
"Tailoring activity and stability: Effects of electronic variations on iron-NHC epoxidation catalysts"
J. Catalysis, 2023, 426, 234-246.
K. Bleher, P. Comba, D. Kass, K. Ray, and H. Wadepohl
"Reactivities of iron(IV)-oxido compounds with pentadentate bispidine ligands"
J. Inorg. Biochem., 2023, 241, 112123.
K. Bleher, P. Comba, J. Gross, and T. Josephy
"ESI and tandem MS for mechanistic studies of high-valent metal complexes"
Dalton Trans., 2022, 51, 8625-8639.
P. Comba, G. Nunn, F. Scherz, P. H. Walton
"Intermediate-spin iron(IV)-oxido species with record reactivity"
Faraday Discuss., 2022, 234, 232-244.
F. L. B. Röhs, S. Dammers, A. Stammler, J. Oldengott, H. Bögge, E. Bill, and T. Glaser
"Dinuclear Diferrous Complexes of a Bis(tetradentate) Dinucleating Ligand: Influence of the Exogenous Ligands on the Molecular and Electronic Structures"
Eur. J. Inorg. Chem., 2022, e202200177.
S. Walleck, T. P. Zimmermann, H. Hachmeister, C. Pilger, T. Huser, S. Katz, P. Hildebrandt, A. Stammler, H. Bögge, E. Bill, and T. Glaser
"Generation of a µ-1,2-hydroperoxo FeIIIFeIII and a µ-1,2-peroxo FeIIIFeIV Complex"
Nat. Commun., 2022, 13, 1376.
F. Depenbrock, T. Limpke, A. Stammler, J. Oldengott, H. Bögge, and T. Glaser
"Molecular and Electronic Structures of a Series of Dinuclear CoII Complexes Varied by Exogenous Ligands: Influence of π-Bonding on Redox Potentials"
Eur. J. Inorg. Chem., 2022, e202100992.